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Reaction-Phase-Selective Inter- and Intramolecular Photochemical Reaction of 2-Pyridone Derivatives

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https://figshare.com/articles/dataset/Reaction_Phase_Selective_Inter_and_Intramolecular_Photochemical_Reaction_of_2_Pyridone_Derivatives/3347818
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资源简介:
Phase-selective photochemical reaction of 2-pyridone derivatives was examined. Irradiation of 1 in benzene mainly gave rearrangement products 2. However, intermolecular [4 + 4] photocycloaddition proceeded quantitatively in the solid state, affording photodimers 3. An effective π−π stacking and dipole−dipole interaction between two pyridone moieties might play important roles in an effective arrangement of 1 for photodimerization in their crystal structures.
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2016-05-07
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