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Iron-Catalyzed Hydrosilylation of Aldehydes and Ketones under Solvent-Free Conditions

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Figshare2016-02-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Iron_Catalyzed_Hydrosilylation_of_Aldehydes_and_Ketones_under_Solvent_Free_Conditions/2118301
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Exposure of aldehyde or ketone to 1 mol % BIAN-Fe­(C7H8) complex in the presence of diphenyl silane affords the corresponding protected alcohol in excellent yields, under mild reaction conditions. Aldehydes and ketones are reduced cleanly in the presence of a broad range of functional groups under solvent-free conditions.
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2016-02-12
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