Raw Data from Redox-mediated carbon monoxide release from a manganese carbonyl—implications for physiological CO delivery by CORMs

These worksheets are the raw data for the quantitative mechanistic investigation of the H2O2 oxidation of the water-soluble model complex fac-[Mn(CO)3(Br)(bpCO2)]2–, (A, bpCO22– = 2,2’-bipyridine-4,4’-dicarboxylate dianion). They contain raw spectral data for the experimental studies presented in RSOS-211022 which demonstrate pH-dependent kinetics.

本数据集所附工作表为水溶性模型配合物fac-[Mn(CO)₃(Br)(bpCO₂)]²⁻（记为A，其中bpCO₂²⁻指代2,2'-联吡啶-4,4'-二羧酸二阴离子）的H₂O₂氧化反应定量机理研究的原始数据。工作表收录了RSOS-211022一文所报道的实验研究的原始光谱数据，该实验证实了该反应具有pH依赖的动力学特性。