Catalytic, Enantioselective, Intramolecular Carbosulfenylation of Olefins
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https://figshare.com/articles/dataset/Catalytic_Enantioselective_Intramolecular_Carbosulfenylation_of_Olefins/2420149
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The first catalytic, enantioselective carbosulfenylation of alkenes with an aromatic nucleophile is described, using a BINAM-based selenophosphoramide catalyst. E-Alkyl- and aryl-substituted alkenes afforded tetrahydronaphthalenes with complete diastereospecificity, and generally high enantiomeric ratios.
创建时间：
2016-02-19
