Sequential Coupling of Zincated Hydrazone, Alkenylboronate, and Electrophile That Creates Several Contiguous Stereogenic Centers
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https://figshare.com/articles/dataset/Sequential_Coupling_of_Zincated_Hydrazone_Alkenylboronate_and_Electrophile_That_Creates_Several_Contiguous_Stereogenic_Centers/3316606
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资源简介：
A zincated N,N-dimethylhydrazone of a ketone undergoes stereospecific syn addition to E- or Z-alkenylboronate to generate a γ-Zn/B dimetallic intermediate, which reacts with a carbon electrophile to give a γ-borylhydrazone in good yield with excellent diastereoselectivity, creating two to four contiguous stereogenic centers in a one-pot reaction.
创建时间：
2016-05-06
