A Room-Temperature-Stable Phosphanorcaradiene
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https://figshare.com/articles/dataset/A_Room-Temperature-Stable_Phosphanorcaradiene/6480278
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资源简介：
A room-temperature-stable
crystalline phosphanorcaradiene 2 has been synthesized
via a C–C bond forming strategy
induced by the demetalation of a phosphepine-Au complex 1 using a Lewis base (Ph3P, IDipp or CyNC). Compound 2 undergoes photolysis to afford a 2H-phosphirene 4. Ru(PPh3)3Cl2 is shown
to catalyze the equilibration of 2 and 4 in solution. In addition, the transformation of 2 to 4 can be achieved by a two-step strategy, namely cyclopropenylidene-induced
ring opening to give cyclopropenylidene-stabilized vinylphosphinidene 7 followed by elimination of cyclopropenylidene by an electrophile
including TMSOTf and Me2SBH3.
创建时间：
2018-06-11
