Operando Insights on the Direct Oxidation of Methane over Fe-SSZ-13
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下载链接：
https://doi.esrf.fr/10.15151/ESRF-ES-1848688257
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资源简介：
Based on prior knowledge regarding the interaction of N2O/O2 and CH4 with Fe in Fe-SSZ-13, this proposal aims to use an operando multi-spectroscopy approach including RIXS, KBeta-HERFD-XAS, and KBeta,alfa-XES to elucidate the temperature-dependent reaction mechanism of CH4 hydroxylation to CH3OH and to isolate the atomic-scale reactivity of active Fe centres. This includes monitoring the Fe oxidation state, the structure of intermediates (Fe-O), spin dynamics, and preferential ligation as a function of reaction conditions.
提供机构：
Paul Scherrer Insitut,General Energy Research Department,PSI-Villigen,5232 VILLIGEN,SWITZERLAND,5232,VILLIGEN,SWITZERLAND; Paul Scherrer Institut; Paul Scherrer Institut,SWITZERLAND,5232 ,VILLIGEN,SWITZERLAND; ESRF,CS 40220,38043 GRENOBLE Cedex 9,FRANCE,38043,GRENOBLE,FRANCE
创建时间：
2027-01-01
