Enantioselective Synthesis of (−)-LL-C10037α from Benzoquinone
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_-LL-C10037_from_Benzoquinone/3761010
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资源简介：
The enantioselective total synthesis of the Streptomyces metabolite (−)-LL-C10037α has been accomplished in 10 steps and 20% overall yield.
An early chiral intermediate was resolved with Candida rugosa lipase to provide (+)-5 with an enantiomeric excess ≥98%. The synthesis is
notable in that no protecting groups are required and that all carbons in the core structure of LL-C10037α are derived from the readily
available p-benzoquinone.
创建时间：
2016-08-26
