Characterization of the E Isomer of Tetrasubstituted [5]Cumulene and Trapping of the Z Isomer as a Zirconocene Complex
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Characterization_of_the_i_E_i_Isomer_of_Tetrasubstituted_5_Cumulene_and_Trapping_of_the_i_Z_i_Isomer_as_a_Zirconocene_Complex/2632155
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资源简介：
The E isomer of a [5]cumulene derivative, 2,2,9,9-tetramethyl-3,8-diphenyldeca-3,4,5,6,7-pentaene (1), which was previously believed to be unisolable owing to very fast E/Z isomerization, was isolated and structurally characterized. The Z isomer was trapped as the transition-metal complex 5, and the molecular structure was determined. DFT calculations and an electrochemical study on 1 are also described.
创建时间：
2016-02-23
