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An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2‘-bithiazoline)(N<sub>3</sub>)<sub>2</sub>]<i><sub>n</sub></i>

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A novel end-on azide-bridged homospin 1D chain, Co(bt)(N3)2 (1) (bt = 2,2‘-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5−6 K, typical of single-chain magnet behavior.

创建时间:
2003-11-19
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