Steric Effect of a Capping Ligand on the Formation of Supramolecular Coordination Networks of Ni(II): Solid-State Entrapment of Cyclic Water Dimer

Supramolecular
dimer of water is the simplest of the small water
clusters [(H2O)n, n = 2–10]. During the course of our work on supramolecular
coordination networks of three-component systems (divalent metal ion,
tridentate capping ligand, and ditopic carboxylate linker), a cyclic
water dimer is found to be entrapped in the network of [Ni2(6-Mebpta)2(adc)2]·2H2O (1) (6-Mebpta = 2-methyl-N-((6-methylpyridin-2-yl)­methyl)-N-(pyridin-2-ylmethyl)­propan-2-amine and adc = acetylenedicarboxylate).
Based on the single-crystal structure of 1, the water
dimer plays an important role in connecting the bis­(adc) bridged dinickel
synthons to form a one-dimensional (1D) supramolecular network. To
emphasize the role of 6-Mebpta in the judicious choice of components
for 1, one simple modification to it by having another
methyl group in the second pendant pyridyl group to make 6,6′-Me2bpta (2-methyl-N,N-bis­((6-methylpyridin-2-yl)­methyl)­propan-2-amine)
did not allow the formation of any water cluster in [Ni­(6,6′-Me2bpta)­(adc)­(H2O)]·H2O (2), where a different coordination environment around Ni­(II) is also
observed. Further quantification of the difference in supramolecular
interactions observed in 1 and 2 has been
assessed by Hirshfeld surface analysis. Both 1 and 2 are obtained in good yields at room temperature (methanol
as solvent) and are further characterized by elemental analysis, Fourier
transform infrared (FTIR) and Raman spectroscopy, powder X-ray diffraction,
and thermogravimetric analysis.