Silver-Catalyzed Decarboxylative Addition/Cyclization of Activated Alkenes with Aliphatic Carboxylic Acids
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https://figshare.com/articles/dataset/Silver_Catalyzed_Decarboxylative_Addition_Cyclization_of_Activated_Alkenes_with_Aliphatic_Carboxylic_Acids/2071228
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资源简介:
A silver-catalyzed
decarboxylative addition/aryl migration/desulfonylation
of N-phenyl-N-(phenylsulfonyl)methacrylamide
with primary, secondary, and tertiary carboxylic acids was described.
The protocol provides an efficient approach for the synthesis of α-all-carbon
quaternary stereocenters amides and isoquinolinediones. It was proposed
that the radical generated from the silver-catalyzed decarboxylation
was involved in the sequence reaction.
创建时间:
2016-02-04



