Synthesis of Unsymmetrically Substituted 4,6,10-Trihydroxy-1,4,6,10-tetraazaadamantanes via Intramolecular Cyclization of Tris(β-oximinoalkyl)amines
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http://www.thieme-connect.com/DOI/DOI?10.1055/s-0031-1289735
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资源简介：
The cyclotrimerization of oximino groups in unsymmetrically substituted tris(β-oximinoalkyl)amines was studied. A general approach to the synthesis of 4,6,10-trihydroxy-1,4,6,10-tetraazaadamantanes
containing different substituents at bridgehead carbon atoms was developed from available aliphatic nitro compounds.
本研究针对不对称取代三(β-肟基烷基)胺分子中肟基的环三聚反应展开了系统研究。从易得的脂肪族硝基化合物出发，开发出一种通用合成策略，可制备桥头碳原子上带有不同取代基的4,6,10-三羟基-1,4,6,10-四氮杂金刚烷。
提供机构：
Georg Thieme Verlag, Stuttgart, New York
创建时间：
2012-03-20
