Titanium−Group 2 Metal Molecular Nitrides
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https://figshare.com/articles/dataset/Titanium_Group_2_Metal_Molecular_Nitrides/3772965
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资源简介：
Treatment of [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)]
with magnesium amido/cyclopentadienyl/alkyl derivatives [MgR2(THF)n] (1 equiv) gives single cube-type
molecular nitrides [RMg{(μ3-N)(μ3-NH)2Ti3(η5-C5Me5)3(μ3-N)}]. Analogous reactions with 0.5 equiv of [M{N(SiMe3)2}2(THF)2] (M = Mg, Ba) afford the corner-shared double-cube nitrido complexes [M{(μ3-N)(μ3-NH)2Ti3(η5-C5Me5)3(μ3-N)}2].
创建时间：
2016-08-26
