Well-Defined Chiral Gold(III) Complex Catalyzed Direct Enantioconvergent Kinetic Resolution of 1,5-Enynes
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https://figshare.com/articles/dataset/Well-Defined_Chiral_Gold_III_Complex_Catalyzed_Direct_Enantioconvergent_Kinetic_Resolution_of_1_5-Enynes/5272423
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资源简介：
The development of
a gold(III) catalyzed direct enantioconvergent
1,5-enyne cycloisomerization and kinetic resolution reaction is described.
The transformation results in highly enantioenriched bicyclo[3.1.0]hexenes
at all levels of conversion, with no racemization or symmetrization
taking place during the course of the reaction, and simultaneously
affords optically enriched 1,5-enynes. This report marks the first
highly enantioselective transformation catalyzed by a well-defined
cationic gold(III) catalyst and demonstrates the unique potential
of gold(III) complexes in enantioselective catalysis.
创建时间：
2017-08-03
