Recognition-Mediated Facilitation of a Disfavored Diels−Alder Reaction
收藏NIAID Data Ecosystem2026-03-06 收录
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The rational design of a system which is capable of accelerating and facilitating a thermodynamically disfavored Diels−Alder cycloaddition between a furan and a maleimide is presented. The origins of the acceleration and facilitation of the cycloaddition reaction are traced by kinetic studiesallied to results from 1H NMR spectroscopy and X-ray crystallographyto the formation of strong intramolecular hydrogen bonds in the cycloadduct.
创建时间：
2016-08-26
