Asymmetric Total Synthesis of Cerorubenic Acid-III
收藏Figshare2019-02-07 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Asymmetric_Total_Synthesis_of_Cerorubenic_Acid-III/7692002
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资源简介：
The first asymmetric total synthesis of the highly strained compound cerorubenic acid-III is reported. A type II intramolecular [5 + 2] cycloaddition allowed efficient and diastereoselective construction of the synthetically challenging bicyclo[4.4.1] ring system with a strained bridgehead (anti-Bredt) double bond in the final product. A unique transannular cyclization installed the vinylcyclopropane moiety with retention of the desired stereochemistry.
创建时间：
2019-02-07
