A Convenient Method for the Synthesis of 2,5-Difunctionalized Phospholes Bearing Ester Groups
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https://figshare.com/articles/dataset/A_Convenient_Method_for_the_Synthesis_of_2_5_Difunctionalized_Phospholes_Bearing_Ester_Groups/3069499
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资源简介:
Symmetrically and unsymmetrically 2,5-difunctionalized
phospholes bearing ester groups were prepared in a one-pot
procedure from the corresponding diynes and dichloro(phenyl)phosphine via titanacyclopentadienes. The observed
optical properties of the functionalized phospholes show that
the π-conjugative push−pull interaction between the 2- and
5-substituents plays an important role in controlling the light-emitting efficiency.
创建时间:
2016-03-01



