five

Gram-Scale Synthesis of a Bench-Stable 5,5″-Unsubstituted Terpyrrole

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https://figshare.com/articles/dataset/Gram-Scale_Synthesis_of_a_Bench-Stable_5_5_-Unsubstituted_Terpyrrole/6738848
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The controlled preparation of higher order oligopyrrolic species holds broad utility across the chemical and material sciences. Here, we describe the gram-scale synthesis of a bench-stable 5,5″-unsubstituted terpyrrole in excellent yield via a tandem Suzuki cross-coupling with in situ deprotection. The solution and solid-state stability as well as UV–vis, fluorescence, and single crystal X-ray diffraction structure are also detailed.
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2018-07-03
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