Enantioselective Carbenoid Insertion into Phenolic O–H Bonds with a Chiral Copper(I) Imidazoindolephosphine Complex
收藏NIAID Data Ecosystem2026-03-09 收录
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The enantioselective O–H carbenoid insertion reaction with a new chiral copper(I) imidazoindolephosphine complex has been developed. The chiral copper(I) complex catalyzed the insertion of carbenoids derived from α-diazopropionates into the O–H bonds of various phenol derivatives to give the corresponding α-aryloxypropionates with up to 91% ee.
创建时间：
2016-02-22
