The application scope of metal–organic frameworks (MOFs) is severely restricted by their weak chemical stability and limited pore size. A robust MOF with large mesopores is highly desired, yet poses a
Highly connected and edge-transitive nets are of prime importance in crystal chemistry and are regarded as ideal blueprints for the rational design and construction of metal–organic frameworks (MOFs).
Small changes to the reaction conditions differentiate between two metal–organic frameworks (MOFs), {[Ce2(H2O)(bpdc)3(dmf)2]·2(dmf)}n (1) and {[Ce4(H2O)5(bpdc)6(dmf)]·x(dmf)}n (2), that were solvoth
Controllable induction of chiral and achiral topological isomers in metal–organic frameworks (MOFs) from achiral tectons remains a challenge. This study demonstrates the tunable growth of an achiral t
The development of porous metal–organic framework (MOF) solids displaying efficient separation and purification of acetylene is of cardinal significance but challenging in the chemical industry. Among
