Regioselective Decarboxylative Transformations of Tetrahydro-β-carboline-1-carboxylic Acid: Reagent Controlled Selectivity toward Alkynylated or Enaminone Products
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https://figshare.com/articles/dataset/Regioselective_Decarboxylative_Transformations_of_Tetrahydro-_-carboline-1-carboxylic_Acid_Reagent_Controlled_Selectivity_toward_Alkynylated_or_Enaminone_Products/24243495
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资源简介：
A one-pot, regioselective decarboxylative alkynylation
of tetrahydro-β-carboline-1-carboxylic
acid under peroxide-free condition is reported. The reaction is highly
selective for the 1-position over the 3-position of tetrahydro-β-carboline.
The reaction can afford alkynylated or enaminone products depending
on the reagent. The reaction proceeds through sequential decarboxylative
iminium ion formation followed by an alkynylation and oxidative rearrangement
cascade.
创建时间：
2023-10-04
