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Regioselective Manipulation of GlcNAc Provides Allosamine, Lividosamine, and Related Compounds

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NIAID Data Ecosystem2026-03-10 收录
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Palladium-catalyzed oxidation of isopropyl N-acetyl-α-d-glucosamine (GlcNAc) is used to prepare the rare sugars allosamine, lividosamine, and related compounds with unprecedented selectivity. The Passerini reaction applied on 3-keto-GlcNAc provides an entry into branching of the carbon skeleton in this compound.

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2019-01-02
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