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Materials Data on LiNbO3 by Materials Project|材料科学数据集|晶体结构数据集
收藏Mendeley Data2024-01-31 更新2024-06-28 收录
下载链接：
https://www.osti.gov/servlets/purl/1731774/
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LiNbO3 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded to five O2- atoms to form distorted LiO5 trigonal bipyramids that share corners with four NbO6 octahedra, corners with two equivalent LiO5 trigonal bipyramids, edges with two NbO6 octahedra, and edges with two LiO5 trigonal bipyramids. The corner-sharing octahedra tilt angles range from 29–65°. There are a spread of Li–O bond distances ranging from 2.05–2.23 Å. In the second Li1+ site, Li1+ is bonded to five O2- atoms to form distorted LiO5 trigonal bipyramids that share corners with two NbO6 octahedra, corners with two equivalent LiO5 trigonal bipyramids, edges with four NbO6 octahedra, and an edgeedge with one LiO5 trigonal bipyramid. The corner-sharing octahedra tilt angles range from 23–52°. There are a spread of Li–O bond distances ranging from 1.97–2.20 Å. There are two inequivalent Nb5+ sites. In the first Nb5+ site, Nb5+ is bonded to six O2- atoms to form distorted NbO6 octahedra that share corners with two equivalent NbO6 octahedra, corners with two LiO5 trigonal bipyramids, edges with three NbO6 octahedra, and edges with three LiO5 trigonal bipyramids. The corner-sharing octahedra tilt angles range from 20–23°. There are a spread of Nb–O bond distances ranging from 1.88–2.19 Å. In the second Nb5+ site, Nb5+ is bonded to six O2- atoms to form distorted NbO6 octahedra that share corners with two equivalent NbO6 octahedra, corners with four LiO5 trigonal bipyramids, edges with two equivalent NbO6 octahedra, and edges with three LiO5 trigonal bipyramids. The corner-sharing octahedra tilt angles range from 20–23°. There are a spread of Nb–O bond distances ranging from 1.83–2.33 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted rectangular see-saw-like geometry to one Li1+ and three Nb5+ atoms. In the second O2- site, O2- is bonded to three Li1+ and one Nb5+ atom to form distorted edge-sharing OLi3Nb trigonal pyramids. In the third O2- site, O2- is bonded in a T-shaped geometry to one Li1+ and two Nb5+ atoms. In the fourth O2- site, O2- is bonded in a distorted rectangular see-saw-like geometry to two Li1+ and two Nb5+ atoms. In the fifth O2- site, O2- is bonded in a rectangular see-saw-like geometry to two Li1+ and two Nb5+ atoms. In the sixth O2- site, O2- is bonded in a trigonal planar geometry to one Li1+ and two Nb5+ atoms.
创建时间：
2024-01-31
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