Parallels between the Chemistry of Calcium(II) and Ytterbium(II). Synthesis and Crystal Structure of a Calcium Alkoxo-Phosphide Cuboidal Complex
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https://figshare.com/articles/dataset/Parallels_between_the_Chemistry_of_Calcium_II_and_Ytterbium_II_Synthesis_and_Crystal_Structure_of_a_Calcium_Alkoxo-Phosphide_Cuboidal_Complex/3762849
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资源简介：
Metathesis between CaI2 and K[P{CH(SiMe3)2}(C6H4-2-OMe)] in THF yields the alkoxo-phosphide complex [Ca{P(CH[SiMe3]2)(C6H4-2-O)}(THF)]4·4THF (2) via a ligand cleavage
reaction involving the migration of a methyl group from oxygen to phosphorus. X-ray
crystallography shows that 2 contains a Ca4O4 cuboidal core with μ2-phosphide groups
bridging four of the faces of the cuboid.
创建时间：
2016-08-26
