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Synthesis of N‑Acylamidines via Rhodium-Catalyzed Reaction of Nitrosobenzene Derivatives with N‑Sulfonyl-1,2,3-triazoles

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Figshare2016-02-16 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_i_N_i_Acylamidines_via_Rhodium_Catalyzed_Reaction_of_Nitrosobenzene_Derivatives_with_i_N_i_Sulfonyl_1_2_3_triazoles/2223871
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资源简介:
α-Imino rhodium carbene, readily generated from N-sulfonyl-1,2,3-triazole, underwent cycloaddition and subsequent rearrangement with a nitrosobenzene derivative to afford N-acylamidine. The unprecedented C–C bond cleavage of α-imino carbene was facilitated by the weakness of the N–O bond.
创建时间:
2016-02-16
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