Upside Down! Crystallographic and Spectroscopic Characterization of an [FeIV(Osyn)(TMC)]2+ Complex
收藏Figshare2016-02-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Upside_Down_Crystallographic_and_Spectroscopic_Characterization_of_an_Fe_sup_IV_sup_O_sub_syn_sub_TMC_sup_2_sup_Complex/2102281
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FeII(TMC)(OTf)2 reacts with 2-tBuSO2–C6H4IO to afford an oxoiron(IV) product, 2, distinct from the previously reported [FeIV(Oanti)(TMC)(NCMe)]2+. In MeCN, 2 has a blue-shifted near-IR band, a higher ν(FeO), a larger Mössbauer quadrupole splitting, and quite a distinct 1H NMR spectrum. Structural analysis of crystals grown from CH2Cl2 reveals a complex with the formulation of [FeIV(Osyn)(TMC)(OTf)](OTf) and the shortest FeIVO bond [1.625(4) Å] found to date.
创建时间：
2016-02-12
