Ambient-Temperature Spin-State Switching Achieved by Protonation of the Amino Group in [Fe(H<sub>2</sub>Bpz<sub>2</sub>)<sub>2</sub>(bipy-NH<sub>2</sub>)]
收藏NIAID Data Ecosystem2026-03-09 收录
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Magnetism of a complex [Fe(H2Bpz2)2(bipy-NH2)] (H2Bpz2 = dihydrobis(1-pyrazolyl)borate, bipy-NH2 = 4,4′-diamino-2,2′-bipyridine) has been altered from paramagnetic to spin-crossover (SCO) behavior, through protonation of one amino group of bipy-NH2 with CF3SO3H. Complete SCO transition, both in solid state and in solution, occurs at ambient temperature.
创建时间：
2016-08-09
