In Solution Sensitization of Er(III) Luminescence by the 4-Tetrathiafulvalene-2,6-pyridinedicarboxylic Acid Dimethyl Antenna Ligand
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https://figshare.com/articles/dataset/In_Solution_Sensitization_of_Er_III_Luminescence_by_the_4_Tetrathiafulvalene_2_6_pyridinedicarboxylic_Acid_Dimethyl_Antenna_Ligand/2560495
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资源简介:
In the [Er(hfac)3(L)]2 complex (1) (L = 4-tetrathiafulvalene-2,6-pyridinecarboxylic
acid dimethyl ester), the Er(III) ion is bonded to the tridentate
coordination site. Electrochemical and photophysical measurements
in solution reveal that the tetrathiafulvalene moiety is a versatile
antenna for erbium luminescence sensitization at 6540 cm–1 upon excitation in the low-energy charge transfer transition (donor
to acceptor charge transfer) at 16600 cm–1 assigned
via time-dependent density functional theory calculations.
创建时间:
2012-01-16



