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Extending the Series: Synthesis and Characterization of a Dicationic N-Heterocyclic Selenium Carbene Analogue

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https://figshare.com/articles/dataset/Extending_the_Series_Synthesis_and_Characterization_of_a_Dicationic_N_Heterocyclic_Selenium_Carbene_Analogue/3055699
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The room-temperature reaction between the Dipp2DAB ligand, SnCl2, and SeCl4 results in the quantitative formation of a dicationic N-heterocyclic “carbenoid”. This represents the first example of a chalcogenium dication that mimics the ubiquitous Arduengo-type carbenes; however, the electronic structure is significantly different.
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2006-10-04
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