Iterative Synthesis of 1,3,5-Polyphenylene Dendrons via C−H Activation
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
An iterative synthesis of 1,3,5-polyphenylene dendrons via C−H activation/Suzuki−Miyaura coupling up to a third generation dendron is described. C−H bonds at the focal points of the dendrons are selectively borylated via iridium-catalyzed borylation, eliminating the need for reactive protecting groups. Sequential additions of low catalyst loadings efficiently borylate higher-generation dendrons, whereas higher initial catalyst loadings are less efficient.
创建时间：
2008-11-06
