Directing Group Enhanced Carbonylative Ring Expansions of Amino-Substituted Cyclopropanes: Rhodium-Catalyzed Multicomponent Synthesis of N‑Heterobicyclic Enones
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https://figshare.com/articles/dataset/Directing_Group_Enhanced_Carbonylative_Ring_Expansions_of_Amino_Substituted_Cyclopropanes_Rhodium_Catalyzed_Multicomponent_Synthesis_of_N_Heterobicyclic_Enones/2023038
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资源简介：
Aminocyclopropanes equipped with
suitable N-directing groups undergo
efficient and regioselective Rh-catalyzed carbonylative C–C
bond activation. Trapping of the resultant metallacycles with tethered
alkynes provides an atom-economic entry to diverse N-heterobicyclic
enones. These studies provide a blueprint for myriad N-heterocyclic
methodologies.
创建时间：
2015-12-16
