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Nuclearity Control of a Trisaloph Zinc Cluster Complex Dependent on Minute Structural Differences in the Bridging Anions

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NIAID Data Ecosystem2026-03-07 收录
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The Zn6 cluster complex 2 of the trisaloph ligand was synthesized using EtCO2– anions as bridging ligands. Complex 2 has a dimeric structure in the crystalline state, while two monomeric isomers were in equilibrium in solution. The anion-exchange reaction successfully resulted in nuclearity control from Zn7 to Zn6.

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2011-06-20
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