five

Formation of Unusual Iridabenzene and Metallanaphthalene Containing Electron-Withdrawing Substituents

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https://figshare.com/articles/dataset/Formation_of_Unusual_Iridabenzene_and_Metallanaphthalene_Containing_Electron-Withdrawing_Substituents/3651951
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资源简介:
A new route to irida-aromatic derivatives which consists of the oxidation of bicyclic compounds has been disclosed. The iridanaphthalene 3 experiences hydrolytic cleavage of the Ir-carboxylate moiety regenerating the bicyclic structure 5, whereas treatment of 5 with ClC(O)CO2Me yields back the metalla-aromatic 3.
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2016-08-18
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