Materials Data on K(MoS)3 by Materials Project

K(MoS)3 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. K is bonded in a trigonal planar geometry to three equivalent S atoms. All K–S bond lengths are 3.11 Å. Mo is bonded in a distorted see-saw-like geometry to four equivalent S atoms. There are a spread of Mo–S bond distances ranging from 2.49–2.60 Å. S is bonded in a 5-coordinate geometry to one K and four equivalent Mo atoms.

K(MoS)₃结晶于六方晶系P6₃/m空间群。该结构为三维结构。K原子以平面三角形配位几何构型与3个等价的S原子成键，所有K–S键长均为3.11 Å。Mo原子以变形跷跷板型配位几何构型与4个等价的S原子成键，Mo–S键距范围为2.49~2.60 Å。S原子以五配位几何构型与1个K原子和4个等价的Mo原子成键。