生物质氢解催化剂研究

生物质氢解催化剂研究数据是由长春应化所提供的有关钯锌甘油氢解催化剂，镍基纤维素氢解催化剂，Ru基油酯氢解催化剂的结构性质及相关反应数据。主要记录了钯锌催化剂催化甘油氢解制备1,2-丙二醇的反应数据和反应机理研究，钯锌催化剂的表面结构、电子性质等结构信息；大孔碳负载的镍基催化剂氢解纤维素制备多元醇的反应数据和大孔碳催化剂的孔结构信息，表面的酸性位点分布和酸量信息，镍催化剂的活性位信息等；氧化钛负载的钌基催化剂氢解硬脂酸酯制长链烷烃的反应数据等（包括反应数据，X射线粉末衍射数据，X射线光电子能谱数据，核磁数据，高分辨透射电镜数据，红外数据等）The research data on biomass hydrogenolysis catalysts, provided by Changchun Institute of Applied Chemistry (CIAC), encompasses structural properties and associated reaction data for three categories of catalysts: palladium-zinc glycerol hydrogenolysis catalysts, nickel-based cellulose hydrogenolysis catalysts, and Ru-based fatty acid ester hydrogenolysis catalysts. This dataset primarily records the reaction data and reaction mechanism studies for palladium-zinc catalyzed glycerol hydrogenolysis to synthesize 1,2-propanediol, alongside structural information of the palladium-zinc catalysts including their surface structure and electronic properties. It further includes reaction data for the hydrogenolysis of cellulose over macroporous carbon-supported nickel-based catalysts to produce polyols, as well as structural details of the macroporous carbon supports such as pore structure, surface acidic site distribution and acid site amount, plus the active site information of the nickel catalysts. Additionally, the dataset contains reaction data for the hydrogenolysis of stearic acid esters over titanium oxide-supported ruthenium-based catalysts to produce long-chain alkanes, covering various characterization data including X-ray powder diffraction (XRD) data, X-ray photoelectron spectroscopy (XPS) data, nuclear magnetic resonance (NMR) data, high-resolution transmission electron microscopy (HRTEM) data, and Fourier-transform infrared spectroscopy (FTIR) data.

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背景与挑战

背景概述

该数据集聚焦于生物质氢解催化剂的研究，涵盖了钯锌、镍基和钌基催化剂在甘油、纤维素和硬脂酸酯氢解反应中的结构性质与反应数据。它包括催化剂的表面结构、电子性质、孔结构、酸性位点分布以及X射线衍射、光电子能谱等多种表征数据。