Structural Consequences of an Extreme Difference between the Trans Influence of the Donor Atoms in a Palladacycle
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The (piperidinomethyl)silylmethyl group in the palladacycles presented here offers one of the largest differences between the trans influence of both donor atoms present. This allows studying distortions of the coordinated 1,5-cyclooctadiene or cyclopentadienyl (Cp) ligands. In the latter case, a strong distortion toward η3-Cp is detected.
创建时间：
2016-02-16
