Three Different Reactions, One Catalyst: A Cu(I) PNP Pincer Complex as Catalyst for C–C and C–N Cross-Couplings
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https://figshare.com/articles/dataset/Three_Different_Reactions_One_Catalyst_A_Cu_I_PNP_Pincer_Complex_as_Catalyst_for_C_C_and_C_N_Cross-Couplings/4871816
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An air-stable, thermally robust, and well-defined Cu(I) PNP pincer complex based on the 2,6-diaminopyridine scaffold is described. This complex is an active catalyst for the cross-couplings of a range of aryl and heteroaryl (including benzoxazole, thiazole, pyridine, and thiophene) halides with different organomagnesium reagents, alkynes, and aryl-amines giving excellent to good isolated yields.
创建时间:
2017-04-12



