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Stable Phosphonium Sila-ylide with Reactivity as a Sila-Wittig Reagent

NIAID Data Ecosystem2026-03-06 收录

数据链接：

https://figshare.com/articles/dataset/Stable_Phosphonium_Sila_ylide_with_Reactivity_as_a_Sila_Wittig_Reagent/2847325 数据链接链接失效反馈

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Stable Phosphonium Sila-ylide with Reactivity as a Sila-Wittig Reagent

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创建时间：

2009-07-01

有机硅化学

光响应材料

Several organosilicon compounds bearing a 2-(phenylazo)phenyl group were synthesized from the corresponding chlorosilanes and 2-lithioazobenzene prepared by halogen−lithium transmetalation of 2-iodoaz

NIAID Data Ecosystem100

Stable Silaimines with Three- and Four-Coordinate Silicon Atoms

有机硅化学

亚胺合成

The reactions of silylenes with organic azides are quite diverse, depending on the substituents of the silylene center and on the nature of the azide employed. Elusive silaimine with three-coordinate

Figshare2016-02-20 更新60

A New Type of N-Heterocyclic Silylene with Ambivalent Reactivity

有机硅化学

反应机理

The synthesis of a novel divalent silicon compound by debromination of the corresponding dibromosilyl precursor is reported. The silylene possesses a unique reactivity toward electrophiles of the type

NIAID Data Ecosystem30

Silver-Catalyzed Silacyclopropenation of 1-Heteroatom-Substituted Alkynes and Subsequent Rearrangement Reactions

有机硅化学

催化反应机理

Silver phosphate-catalyzed silylene transfer from silacyclopropane 1 to 1-heteroatom-substituted alkynes resulted in alkoxy-, amino-, and alkylthiolate-substituted silacyclopropenes. Silver-catalyzed

NIAID Data Ecosystem70

Compound 526094: Tetradecanoic acid, 12-methyl, trimethylsilyl ester

化学化合物分析

有机硅化学

Chemical compound data from PubChem database. IUPAC Name: trimethylsilyl 12-methyltetradecanoate. Molecular Formula: C18H38O2Si. Molecular Weight: 314.6. This dataset...

data.gov30

Stable Phosphonium Sila-ylide with Reactivity as a Sila-Wittig Reagent

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