Data from: Understanding the biogeochemical and spatial drivers of methane and carbon dioxide fluxes in a large temperate reservoir

This dataset contains spatially resolved measurements of CO₂ and CH₄ fluxes and associated environmental variables collected across 200 sites in Douglas Reservoir (Tennessee, USA) between July 29-August 2, 2024. Measurements include diffusive fluxes of CO₂ and CH₄, CH₄ ebullition, and biogeochemical and spatial variables such as dissolved oxygen, temperature, conductivity, chlorophyll-a, pH, water depth, and distance from the dam. Sampling was conducted using a spatially balanced design to capture longitudinal and depth-related gradients throughout the reservoir. The dataset is structured to support analyses of spatial variability, flux pathway comparisons, and modeling approaches (e.g., spatial statistics and machine learning) aimed at understanding controls on reservoir CO₂ and CH₄ fluxes and improving upscaling to whole-reservoir and regional estimates.