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Catalytic Diboration of Unsaturated Molecules with Platinum(0)−NHC: Selective Synthesis of 1,2-Dihydroxysulfones

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https://figshare.com/articles/dataset/Catalytic_Diboration_of_Unsaturated_Molecules_with_Platinum_0_NHC_Selective_Synthesis_of_1_2_Dihydroxysulfones/3047065
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资源简介:
Readily available N-heterocyclic platinum complexes provide active catalytic species for 1,2-diboration and anticipate a wide range of applications in alkenes and alkynes. Unprecedented catalytic B−B addition of heteroatom-containing substrates provided high selectivity into organosulfur−diboronate esters. Their in situ basic oxidation afforded the desired 1,2-dihydroxysulfones in high yields.
创建时间:
2006-11-20
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