Asymmetric Synthesis of Axially Chiral Biaryl Diphosphine Ligands by Rhodium-Catalyzed Enantioselective Intramolecular Double [2 + 2 + 2] Cycloaddition
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Asymmetric_Synthesis_of_Axially_Chiral_Biaryl_Diphosphine_Ligands_by_Rhodium_Catalyzed_Enantioselective_Intramolecular_Double_2_2_2_Cycloaddition/2694577
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The concise synthesis of axially chiral biaryl diphosphine ligands by the rhodium-catalyzed intramolecular [2 + 2 + 2] cycloaddition of hexayne diphosphine oxides has been achieved. These new chiral diphosphine ligands could be employed as a ligand for the rhodium-catalyzed asymmetric catalyses.
创建时间：
2016-02-23
