Metal-Free Transfer Hydrogenation Catalysis by B(C6F5)3
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https://figshare.com/articles/dataset/Metal_Free_Transfer_Hydrogenation_Catalysis_by_B_C_sub_6_sub_F_sub_5_sub_sub_3_sub_/2615665
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The activation of amines by B(C6F5)3 is shown to effect the catalytic racemization of a chiral amine. Extending this strategy to a bimolecular process, catalytic transfer hydrogenation of imines, enamines, and N-heterocycles is demonstrated using iPr2NH as the source of hydrogen and a catalytic amount of the Lewis acid B(C6F5)3.
创建时间:
2016-02-23



