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Borole Formation by 1,1-Carboboration

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Borole_Formation_by_1_1_Carboboration/2334523
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Bis­(trimethylsilylethynyl)­di­phenyl­amino­borane was reacted with the strong Lewis acid B­(C6F5)3 at ambient temperature to give the borole 9 admixed with a small amount of its thermal follow–up product 12. Compound 9 was subsequently stabilized by adduct formation with pyridine (10). Treatment of bis­(trimethylsilylethynyl)­phenylborane with B­(C6F5)3 gave the borole 14, which reacted with 3-hexyne to give the [4 + 2] cycloaddition product 15.
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2016-02-18
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