Palladacycle-Catalyzed Methylenecyclopropanation of Bicyclic Alkenes with Propiolates
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https://figshare.com/articles/dataset/Palladacycle_Catalyzed_Methylenecyclopropanation_of_Bicyclic_Alkenes_with_Propiolates/2352754
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资源简介：
An
efficient way to access functionalized methylenecyclopropanes
has been developed by palladacycle-catalyzed cyclopropanation of bicyclic
alkenes with propiolates in high yields. The structure of the palladacycle
was kept intact in the reaction, shown by 31P NMR spectrum
studies. A rational mechanism has been proposed with a deuterium-labeled
experiment. The usefulness of the functionalized methylenecyclopropanes
has also been demonstrated.
创建时间：
2016-02-18
