Influence of Cu Addition and Autoclave Sterilization on Corrosion Resistance and Biocompatibility of NiTi for orthodontics Applications

Commercial archwires NiTiCu (Ormco) and NiTi (Morelli) and samples of the corresponding raw materials were tested to assess the influence of Cu addition and sterilization on the corrosion resistance and biocompatibility. Raw materials samples and commercial archwires exhibited similar corrosion resistance when compared. The addition of Cu decreased the corrosion resistance of NiTi alloy, whiling the sterilization process had no influence. The biocompatibility tests were carried out in different extracts of the alloys and no cytotoxicity effects were observed for the ionic concentrations used. SEM and Confocal laser analysis permitted to observe the localized corrosion morphology obtained after anodic polarization tests. Although Cu addition on NiTi can be introduced to better adjust the mechanical resistance, this third element induced detrimental effect on the corrosion resistance of raw materials and commercial archwires.