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Zinc Carbodiimide Cluster Complexes: Synthesis, X-ray Crystal Structures, and Reaction Mechanism

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https://figshare.com/articles/dataset/Zinc_Carbodiimide_Cluster_Complexes_Synthesis_X_ray_Crystal_Structures_and_Reaction_Mechanism/2836807
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资源简介:
Reactions of Me2Zn with carbodiimides C(NR)2 in different molar ratios at elevated temperature were investigated, a possible reaction mechanism was identified, and the single-crystal X-ray structures of polynuclear amidinate zinc complexes {C[C(NCy)2ZnMe]4}, 1, {C[C(NCy)2ZnMe]3(ZnMe)}, 3, and {C[C(NCy)2ZnMe]3(ZnMe)(MeZnOMe)}, 5, are reported.
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2016-02-26
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