A Borenium Cation Stabilized by an N-Heterocyclic Carbene Ligand
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https://figshare.com/articles/dataset/A_Borenium_Cation_Stabilized_by_an_N_Heterocyclic_Carbene_Ligand/2836903
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资源简介：
Reaction of Mes2BF with trimethylsilyl triflate (Me3SiOTf) and [Ag(IMe)2][Ag2I3] (IMe = 1,3-dimethylimidazol-2-ylidene) in refluxing chlorobenzene affords the carbene-stabilized borenium salt [(IMe)BMes2]OTf ([1][OTf]). As indicated by cyclic voltammetry, [1]+ is reversibly reduced to produce a radical that has been characterized by EPR spectroscopy.
创建时间：
2016-02-26
