Selective Retention of Methanol over Ethanol by a Cyclen-Based Cryptand/Copper(II) Complex
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https://figshare.com/articles/dataset/Selective_Retention_of_Methanol_over_Ethanol_by_a_Cyclen_Based_Cryptand_Copper_II_Complex/2364700
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资源简介：
A cyclen-based
cryptand (2) was prepared in a two-step synthesis from
dioxocyclen. When a Cu(CF3SO3)2 complex
with 2 was prepared in methanol, the 2/Cu(CF3SO3)2 complex incorporated one methanol
in the cavity formed by the diethyleneoxy unit and the NH group of
the cyclen. When prepared in ethanol, the 2/Cu(CF3SO3)2 complex similarly incorporated
one ethanol. Cold electrospray ionization mass spectrometry (CSI-MS)
of the 2/Cu(CF3SO3)2/alcohol complexes selectively retains methanol over ethanol under
CSI-MS conditions.
创建时间：
2016-02-18
