Decoding Stereocontrol During the Photooxygenation of Oxazolidinone-Functionalized Enecarbamates
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https://figshare.com/articles/dataset/Decoding_Stereocontrol_During_the_Photooxygenation_of_Oxazolidinone_Functionalized_Enecarbamates/2771104
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资源简介:
Systematically designed oxazolidinone-derived enecarbamates reveal that solvent and temperature effects on the stereoselectivity during photooxygenation are likely due to the conformational flexibility of the chiral phenethyl side chain (entropy factors); the extent of enantiomeric excess in the photoproduct is dictated by the alkene geometry.
创建时间:
2010-05-07



